DISSOCIATION KINETICS STUDY OF Ce(III) COMPLEXES WITH H8dotp (H8dotp = 1,4,7,10-TETRAAZACYCLODODECANE-1,4,7,10-TETRAKIS(METHYLPHOSPHONIC ACID))
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216224%3A14310%2F08%3A00025763" target="_blank" >RIV/00216224:14310/08:00025763 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/08:12782
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
DISSOCIATION KINETICS STUDY OF Ce(III) COMPLEXES WITH H8dotp (H8dotp = 1,4,7,10-TETRAAZACYCLODODECANE-1,4,7,10-TETRAKIS(METHYLPHOSPHONIC ACID))
Original language description
The dissociation kinetics of cerium(III) complexes with H8dotp (I = 3.0 mol dm-3 (Na,H)ClO4, t = 25 - 60 degrees C) was studied by means of molecular absorption spectroscopy in the UV region. The mechanism of the proton-assisted reaction was proposed, and the activation parameters (Ea = 111 +/- 20 kJ mol-1, delta_H_act = 108 +/- 20 kJ mol-1, delta_S_act = 32 +/- 62 J K-1 mol-1) for the rate-determining step were calculated.
Czech name
Studium disociační kinetiky Ce(III) komplexu s H8dotp ligandem
Czech description
Disociační kinetika Ce(III) komplexu s H8dotp ligandem (I = 3.0 mol dm-3 (Na,H)ClO4, t = 25 - 60 st. C) byla studována pomocí mol. abs. spektroskopie. Reakční mechanismus byl navržen a aktivační parametry (Ea = 111 +/- 20 kJ mol-1, delta_H_akt = 108 +/-20 kJ mol-1, delta_S_akt = 32 +/- 62 J K-1 mol-1) pro rychlost určující reakční krok byly vypočteny.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2008
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Alloys and Compounds
ISSN
0925-8388
e-ISSN
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Volume of the periodical
451
Issue of the periodical within the volume
1-2
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
4
Pages from-to
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UT code for WoS article
000253600400007
EID of the result in the Scopus database
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