Characterization of the triple ion [(CH3)(4)N+center dot PF6-center dot(CH3)(4)N+] in the gas-phase

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F10%3A10062553" target="_blank" >RIV/00216208:11310/10:10062553 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Characterization of the triple ion [(CH3)(4)N+center dot PF6-center dot(CH3)(4)N+] in the gas-phase
Original language description
The triple ion [(CH3)(4)N+center dot PF6-center dot(CH3)(4)N+], generated by electrospray ionization of tetramethylammonium hexafluorophosphate, is characterized by collision-induced dissociation and infrared spectroscopy of the mass-selected gaseous ionin the range from 1000 to 2000 cm(-1). Quantum chemical calculations are used to elucidate the structures and energetics of the triple ion and its subunits and for the assignment of the infrared frequencies. The infrared bands observed in the gas-phasematch quite closely with those of the bulk substance, suggesting that for this particular kind of ion associate the structural differences between the gas-phase and the condensed state are almost negligible. (C) 2010 Elsevier B.V. All rights reserved.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/GA203%2F08%2F1487" target="_blank" >GA203/08/1487: Micro-hydration of metal cations in the gas phase</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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