Chiral Separation of Binaphthyl Catalysts Using New Chiral Stationary Phases Based on Derivatized Cyclofructans
The result's identifiers
Result code in IS VaVaI
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Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Chiral Separation of Binaphthyl Catalysts Using New Chiral Stationary Phases Based on Derivatized Cyclofructans
Original language description
Cyclofructans as a completely new and promising class of chiral selectors have been introduced last year for application in separation techniques such as liquid chromatography and capillary electrophoresis. Mainly derivatives of cyclofructans perform interesting separation possibilities for a variety of compounds. The aromatic derivatized cyclofructans composed of six D-fructofuranose units (CF6) have exhibited the most interesting properties and unique enantioselectivity. In this work, two derivatizedcyclofructan-based chiral stationary phases, RN-CF6 ( -naphthylethyl carbamate CF6) and DMP-CF7 (dimethylphenyl carbamate CF7) were used for enantioseparation of substituted binaphtyl catalysts, widely used to control asymmetric processes. Normal separation mode, i.e. mobile phase composed of hexane and propane-2-ol in different ratios was applied and the enantioselectivity of the employed stationary phases was compared.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach<br>V - Vyzkumna aktivita podporovana z jinych verejnych zdroju
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
Proceedings of the 6th International Students Conference"Modern Analytical Chemistry"
ISBN
978-80-7444-005-2
ISSN
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e-ISSN
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Number of pages
4
Pages from-to
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Publisher name
Univerzita Karlova v Praze, Přírodovědecká fakulta
Place of publication
Praha
Event location
Praha, Česká republika
Event date
Sep 23, 2010
Type of event by nationality
CST - Celostátní akce
UT code for WoS article
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