Methods for determination of all binding parameters in systems with simultaneous borate and cyclodextrin complexation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F11%3A10099392" target="_blank" >RIV/00216208:11310/11:10099392 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.chroma.2011.07.088" target="_blank" >http://dx.doi.org/10.1016/j.chroma.2011.07.088</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.chroma.2011.07.088" target="_blank" >10.1016/j.chroma.2011.07.088</a>
Alternative languages
Result language
angličtina
Original language name
Methods for determination of all binding parameters in systems with simultaneous borate and cyclodextrin complexation
Original language description
Two novel methods for determination of binding constants in the systems with borate and cyclodextrin complexation were developed. The methods enable to determine all binding parameters in these systems and even the binding constants of interaction of a neutral analyte with a neutral cyclodextrin. The first method is based on nonlinear fitting of experimental data and further evaluation of fitting parameters. The second method requires a multiple regression. The methods provide identical results with lowexperimental error. Only one set of measurements is required for both methods. Thus the binding parameters can be mutually compared. The binding parameters for neutral analytes ((R,R)-(+)-hydrobenzoin and (S,S)-(-)-hydrobenzoin) and neutral cyclodextrin(heptakis(2,6-di-O-methyl)-beta-cyclodextrin) were evaluated and the effect of individual types of interaction was revealed.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F08%2F1428" target="_blank" >GA203/08/1428: Capillary electrophoresis with multidimensinal detection and its application to separation and characterization of biopolymers</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Chromatography A
ISSN
0021-9673
e-ISSN
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Volume of the periodical
1218
Issue of the periodical within the volume
40
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
8
Pages from-to
7211-7218
UT code for WoS article
000295300600017
EID of the result in the Scopus database
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