Synthesis of quinolines via Friedlander reaction catalyzed by CuBTC metal-organic-framework

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10120339" target="_blank" >RIV/00216208:11310/12:10120339 - isvavai.cz</a>

Alternative codes found

RIV/61388955:_____/12:00389820

Result on the web

<a href="http://dx.doi.org/10.1039/c2dt11978a" target="_blank" >http://dx.doi.org/10.1039/c2dt11978a</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/c2dt11978a" target="_blank" >10.1039/c2dt11978a</a>

Result language

angličtina

Original language name

Synthesis of quinolines via Friedlander reaction catalyzed by CuBTC metal-organic-framework

Original language description

Friedlander condensation between 2-aminoaryl ketones and different carbonyl compounds, catalyzed by CuBTC was investigated by a combination of various experimental techniques and by density functional theory based modelling. CuBTC exhibiting hard Lewis acid character showed highly improved catalytic activity when compared with other molecular sieves showing high concentraion of Lewis acid sites, e.g. in BEA and (Al)SBA-15. Polysubstituted quinolines were synthesized via a Friedlander reaction catalyzedby CuBTC under the solvent-free conditions. High concentration of active sites in CuBTC together with the concerted effect of a pair of adjacent Cu2+ coordinatively unsaturated active sites are behind a very high quinoline yield reached within a short reaction time. Results reported here make CuBTC a promising catalyst for other Lewis acid-promoted condensations, including those leading to biologically active compounds with a particular relevance for the pharmaceutical industry. The mech

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

<a href="/en/project/7E09111" target="_blank" >7E09111: MOFs As Catalysts and Adsorbents: Discovery and Engeneering of Materials for Industrial Applications</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2012

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Dalton Transactions

ISSN

1477-9226

e-ISSN

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Volume of the periodical

41

Issue of the periodical within the volume

14

Country of publishing house

GB - UNITED KINGDOM

Number of pages

9

Pages from-to

4036-4044

UT code for WoS article

000301495500029

EID of the result in the Scopus database

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