Determination of stability constants of complexes of neutral analytes with charged cyclodextrins by affinity capillary electrophoresis
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10120351" target="_blank" >RIV/00216208:11310/12:10120351 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/elps.201100489" target="_blank" >http://dx.doi.org/10.1002/elps.201100489</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/elps.201100489" target="_blank" >10.1002/elps.201100489</a>
Alternative languages
Result language
angličtina
Original language name
Determination of stability constants of complexes of neutral analytes with charged cyclodextrins by affinity capillary electrophoresis
Original language description
A novel procedure for the determination of stability constants in systems with neutral analytes and charged complexation agents by affinity capillary electrophoresis was established. This procedure involves all necessary corrections to achieve precise and reliable data. Temperature, ionic strength, and viscosity corrections were applied. Based on the conductivity measurements, the average temperature of the background electrolyte in the capillary was kept at the constant value of 25 degrees C by decreasing the temperature of the cooling medium. The viscosity correction was performed using the viscosity ratio determined by an external viscosimeter. The electrophoretical measurements were performed, at first, at constant ionic strength. In this case, theincrease of ionic strength caused by increasing complexation agent concentration was compensated by changing of the running buffer concentration. Subsequently the dependence of the analyte effective mobility on the complexation agent con
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GCP205%2F11%2FJ043" target="_blank" >GCP205/11/J043: Complex study of random branched amphiphilic copolymers</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Electrophoresis
ISSN
0173-0835
e-ISSN
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Volume of the periodical
33
Issue of the periodical within the volume
6
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
1032-1039
UT code for WoS article
000303155700018
EID of the result in the Scopus database
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