Poly(disubstituted acetylene)s With Pendant Naphthalimide-Based Fluorophore Groups
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10120354" target="_blank" >RIV/00216208:11310/12:10120354 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/macp.201100509" target="_blank" >http://dx.doi.org/10.1002/macp.201100509</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/macp.201100509" target="_blank" >10.1002/macp.201100509</a>
Alternative languages
Result language
angličtina
Original language name
Poly(disubstituted acetylene)s With Pendant Naphthalimide-Based Fluorophore Groups
Original language description
New stable polyacetylenes whose quantum yield of fluorescence is increased up to 62% because of the presence of pendant 4-(piperidine-1-yl)-1,8-naphtalimide groups are described. The polymers are prepared by two-step modification of copolymers of 1-(4-tert-butylphenyl)-6-chlorohex-1-yne and 1-phenylhex-1-yne consisting of the exchange of chlorine atoms at side groups for azide groups and subsequent Huisgen click reaction of the azide groups with ethynyl groups of N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide. Modification is evidenced by 1H NMR, IR, Raman and UVvis spectroscopy. Modified polymers show the excitation energy transfer from their main chains on fluorophores and nearly preservation of fluorescence properties of fluorophores upontheir binding to polymer chains.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Macromolecular Chemistry and Physics
ISSN
1022-1352
e-ISSN
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Volume of the periodical
213
Issue of the periodical within the volume
4
Country of publishing house
GB - UNITED KINGDOM
Number of pages
14
Pages from-to
411-424
UT code for WoS article
000300568900007
EID of the result in the Scopus database
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