Copolymerization of N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide with arylacetylenes into fluorescent polyacetylene-type conjugated polymers
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F15%3A00445343" target="_blank" >RIV/61389013:_____/15:00445343 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/macp.201500240" target="_blank" >http://dx.doi.org/10.1002/macp.201500240</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/macp.201500240" target="_blank" >10.1002/macp.201500240</a>
Alternative languages
Result language
angličtina
Original language name
Copolymerization of N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide with arylacetylenes into fluorescent polyacetylene-type conjugated polymers
Original language description
N-(prop-1-yne-3-yl)-4-(piperidine-1-yl)-1,8-naphthalimide (PNPr), i.e., the monomer with a terminal ethynyl group and 1,8-naphthalimide fluorophore, has been successfully copolymerized with a series of monoethynylarenes into well-soluble high-molecular-weight (Mw up to 210 000) linear polyacetylene-type copolymers containing from 14 to 51 mol% units derived from PNPr. The copolymerization of PNPr with bifunctional 4,4-diethynylbiphenyl provides polyacetylene-type micro/mesoporous fluorescent network containing 8 mol% PNPr units and exhibiting the Brunauer?Emmett?Teller surface of 1000 m2 g1. The copolymerizations (catalyzed with acetylacetonato(norborna-2,5-diene)rhodium complex, [Rh(nbd)acac]) proceed smoothly despite the fact that the homopolymerization of PNPr fails. The fluorescence of PNPr (emission at 510 nm) has been retained after the incorporation of PNPr into the copolymers. The fluorescence of the copolymers can be induced by a direct excitation of PNPr units or via an energ
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Macromolecular Chemistry and Physics
ISSN
1022-1352
e-ISSN
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Volume of the periodical
216
Issue of the periodical within the volume
21
Country of publishing house
DE - GERMANY
Number of pages
14
Pages from-to
2115-2128
UT code for WoS article
000364340200006
EID of the result in the Scopus database
2-s2.0-84946482956