Crystallization and characterization of the compounds Gly.MSO4.mH2O (M = Mg2+, Mn2+, Fe2+, Co2+, Ni2+, Zn2+; m = 0, 3, 5, 6)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10127269" target="_blank" >RIV/00216208:11310/12:10127269 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/12:00377358
Result on the web
<a href="http://dx.doi.org/10.1016/j.molstruc.2012.02.068" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2012.02.068</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2012.02.068" target="_blank" >10.1016/j.molstruc.2012.02.068</a>
Alternative languages
Result language
angličtina
Original language name
Crystallization and characterization of the compounds Gly.MSO4.mH2O (M = Mg2+, Mn2+, Fe2+, Co2+, Ni2+, Zn2+; m = 0, 3, 5, 6)
Original language description
The equilibrium crystallization of complex compounds of the type Gly.MSO4.5H2O with a structure derived from those of the crystallized double salts MSO4.xH2O, where x = 6, 7 was predicted and proven in the systems Gly-MSO4-H2O (M = Mg2+, Mn2+, Fe2+, Co2+, Ni2+ and Zn2+). It was predicted that stable octahedral complexes [M(H2O)6]2+ and trans-[M(H2O)4(O-gly)2]2+, as well as [SO4]2MINUS SIGN tetrahedra, which were the main building units of the crystallizing Gly.MSO4.5H2O compounds (triclinic crystal system, space group P MINUS SIGN 1), were predominating in these solutions. The vibrational spectra and the thermal behavior of the Gly.MSO4.5H2O compounds (M = Mg2+, Co2+, Zn2+) are in accord with the refined crystal structures. The cobalt compound displaysantiferromagnetic behavior whereas the nickel and manganese compounds are ferromagnetic. In the manganese system where MnSO4.H2O (308 K) crystallizes, the only complex compound is the anhydrous Gly.MnSO4 with a polymeric type structure .
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F09%2F0878" target="_blank" >GA203/09/0878: Crystal engineering of hydrogen bonded materials for non-linear optics</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Molecular Structure
ISSN
0022-2860
e-ISSN
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Volume of the periodical
1018
Issue of the periodical within the volume
březen
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
9
Pages from-to
113-121
UT code for WoS article
000305847100019
EID of the result in the Scopus database
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