Synthesis of Aromatic Compounds by Catalytic C-C Bond Activation of Biphenylene or Angular [3]Phenylene
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10127553" target="_blank" >RIV/00216208:11310/12:10127553 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/12:00377450
Result on the web
<a href="http://dx.doi.org/10.1002/chem.201103888" target="_blank" >http://dx.doi.org/10.1002/chem.201103888</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.201103888" target="_blank" >10.1002/chem.201103888</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis of Aromatic Compounds by Catalytic C-C Bond Activation of Biphenylene or Angular [3]Phenylene
Original language description
Substituted phenanthrenes and picenes were easily prepared by reaction of biphenylene or angular [3]phenylene with various alkynes in the presence of a catalytic amount of [IrCl(cod)]2/dppe (cod=1,5-cyclooctadiene, dppe=1,2-bis(diphenylphosphino)ethane).The reaction is based on C-C bond activation of the cyclobutane ring. The reaction tolerates the presence of bulky groups on the alkyne, such as the ferrocene moiety. In addition, a catalytic system based on [RhCl(cod)]2/dppe enabled the, hitherto unreported, reaction of biphenylene with nitriles to provide phenanthridines.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry - A European Journal
ISSN
0947-6539
e-ISSN
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Volume of the periodical
18
Issue of the periodical within the volume
14
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
4200-4207
UT code for WoS article
000302073700011
EID of the result in the Scopus database
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