Aromatic C-H bond activation revealed by infrared multiphoton dissociation spectroscopy
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10128773" target="_blank" >RIV/00216208:11310/12:10128773 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/12:00377947
Result on the web
<a href="http://dx.doi.org/10.1002/jms.2963" target="_blank" >http://dx.doi.org/10.1002/jms.2963</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/jms.2963" target="_blank" >10.1002/jms.2963</a>
Alternative languages
Result language
angličtina
Original language name
Aromatic C-H bond activation revealed by infrared multiphoton dissociation spectroscopy
Original language description
Metal-oxide cations are models of catalyst mediating the CH bond activation of organic substrates. One of the most powerful reagents suggested in the gas phase is based on CuO+. Here, we describe the activation of the aromatic CH bonds of phenanthrolinein its complex with CuO+. The reaction sequence starts with a hydrogen atom abstraction by the oxygen atom from the 2-position of the phenanthroline ring, followed by OH migration to the ring. Using infrared multiphoton spectroscopy, it is shown that thereaction can be energetically facilitated by additional coordination of a water ligand to the copper ion. As the reaction is intramolecular, a spectroscopic characterization of the product is mandatory in order to unambiguously address the reaction mechanism.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP207%2F11%2F0338" target="_blank" >GAP207/11/0338: Reaction mechanisms in organometallic chemistry</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Mass Spectrometry
ISSN
1076-5174
e-ISSN
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Volume of the periodical
47
Issue of the periodical within the volume
4
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
460-465
UT code for WoS article
000305063400006
EID of the result in the Scopus database
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