All

What are you looking for?

All
Projects
Results
Organizations

Quick search

  • Projects supported by TA ČR
  • Excellent projects
  • Projects with the highest public support
  • Current projects

Smart search

  • That is how I find a specific +word
  • That is how I leave the -word out of the results
  • “That is how I can find the whole phrase”

Synthesis, Molecular Structure, and Electrochemistry of 1-Ferrocenyl-1,2-dicarba-closo-dodecaboranes

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F13%3A10139220" target="_blank" >RIV/00216208:11310/13:10139220 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388963:_____/13:00393413

  • Result on the web

    <a href="http://dx.doi.org/10.1002/ejic.201300110" target="_blank" >http://dx.doi.org/10.1002/ejic.201300110</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/ejic.201300110" target="_blank" >10.1002/ejic.201300110</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis, Molecular Structure, and Electrochemistry of 1-Ferrocenyl-1,2-dicarba-closo-dodecaboranes

  • Original language description

    Bis(dimethylsulfido)decaborane, 6,9-(Me2S)2-arachno-B10H12, reacts smoothly with ferrocenyl alkynes FcCCR [1ah; Fc = ferrocenyl, R = H (1a), CH3 (1b), Ph (1c), 4-MeO2CC6H4 (1d), Fc (1e), CCFc (1f), C(O)CH3 (1g), and CO2CH2CH3 (1h)] to afford the corresponding 1-ferrocenyl-1,2-dicarba-closo-dodecaboranes 2ah in good yields. Ester 2h was further reduced to the respective hydroxymethyl derivative, 1-Fc-2-CH2OH-1,2-closo-C2B10H10 (3). The reaction of 6,9-(Me2S)2-B10H12 with FcCCSiMe3 proceeded in a different manner to produce (among other products) an SMe2 adduct of an opened decaborane substituted with a 2-ferrocenyl-2-(trimethylsilyl)ethen-1-yl group (4). This compound probably results through hydroboration of the starting alkyne and migration of the SiMe3 group. All prepared compounds were characterized by spectroscopic methods (1H, 13C, and 11B NMR spectroscopy, IR spectroscopy, and mass spectrometry), and their molecular structures were determined by single-crystal X-ray diffraction a

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    European Journal of Inorganic Chemistry

  • ISSN

    1434-1948

  • e-ISSN

  • Volume of the periodical

    neuveden

  • Issue of the periodical within the volume

    15

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    10

  • Pages from-to

    2789-2798

  • UT code for WoS article

    000318917700012

  • EID of the result in the Scopus database