Carbon-substituted 9,12-dimercapto-1,2-dicarba-closo-dodecaboranes via a 9,12-bis(methoxy-methylthio)-1,2-dicarba-closo-dodecaborane precursor

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F12%3A00382579" target="_blank" >RIV/68378271:_____/12:00382579 - isvavai.cz</a>

Alternative codes found

RIV/61388980:_____/12:00382579

Result on the web

<a href="http://dx.doi.org/10.1016/j.poly.2012.07.067" target="_blank" >http://dx.doi.org/10.1016/j.poly.2012.07.067</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.poly.2012.07.067" target="_blank" >10.1016/j.poly.2012.07.067</a>

Result language

angličtina

Original language name

Carbon-substituted 9,12-dimercapto-1,2-dicarba-closo-dodecaboranes via a 9,12-bis(methoxy-methylthio)-1,2-dicarba-closo-dodecaborane precursor

Original language description

Dithiolated derivatives of 1,2-dicarba-closo-dodecaboranes are common ligands to be used for self-assembling monolayers, nanoparticles or transition complexes due to their robust molecular structure. The 9,12-dimercapto-1,2- dicarba-closo-dodecaborane, aderivative with two SH-groups in adjacent positions, is an interesting unit for the preparation of derivatives additionally functionalized in positions one and two. In this contribution, we report a convenient synthesis of 1,2-disubstituted 9,12-dimercapto-1,2-dicarba- closo-dodecaboranes starting from the 9,12-dimercapto-1,2-dicarba-closo- dodecaboranes with SH groups protected using methoxy-methyl (MOM) groups. All compounds are well characterized via HiRes-mass spectroscopy, 1H, 13C and 11B NMR-spectroscopy and IR spectroscopy. The precursor 9,12-bis(methoxy-methylthio)-1,2-dicarba-closo-dodecaborane was additionally characterized with X-ray-structural analysis.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BM - Solid-state physics and magnetism

OECD FORD branch

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Project

<a href="/en/project/GAP205%2F10%2F0348" target="_blank" >GAP205/10/0348: Sandwich nanocomposites: preparation, nucleation effects, electrical properties.</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2012

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Polyhedron

ISSN

0277-5387

e-ISSN

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Volume of the periodical

45

Issue of the periodical within the volume

1

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

8

Pages from-to

144-151

UT code for WoS article

000309627000018

EID of the result in the Scopus database

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