Sunlight Photolysis of Decamethyltitanocene Dihydrosulfide Affords the Titanium Sulfide Cage Clusters (Cp*Ti)6S8 and (Cp*Ti)4S6
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F13%3A10141574" target="_blank" >RIV/00216208:11310/13:10141574 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/13:00394695
Result on the web
<a href="http://dx.doi.org/10.1002/ejic.201300391" target="_blank" >http://dx.doi.org/10.1002/ejic.201300391</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201300391" target="_blank" >10.1002/ejic.201300391</a>
Alternative languages
Result language
angličtina
Original language name
Sunlight Photolysis of Decamethyltitanocene Dihydrosulfide Affords the Titanium Sulfide Cage Clusters (Cp*Ti)6S8 and (Cp*Ti)4S6
Original language description
Sunlight photolysis of decamethyltitanocene dihydrosulfide [Cp*2Ti(SH)2] (1, Cp* = 5-C5Me5) in toluene affords the titanium sulfide clusters [(Cp*Ti)6(3-S)8] (4) and [(Cp*Ti)4(3-S)3(2-S)3] (5), the former in very low yield and the latter in good yield. The crystal structures of both compounds are toluene solvates and are based on a nearly regular titanium octahedron for 4 and a trigonal pyramid for 5. The [(Cp*Ti)3(3-S)(2-S)3] (6) complex isolated in a trace amount from the photolysis of 1 in hexane could be a precursor of 4. A plausible mechanism for the formation of 5 and 6 follows a mechanism recently proposed for photolysis of [Cp*2Ti(OH)2] by U. Rosenthal et al.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP207%2F12%2F2368" target="_blank" >GAP207/12/2368: Group 4 metallocenes: activation of ligands for synthetic and catalytic applications</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
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Volume of the periodical
neuveden
Issue of the periodical within the volume
19
Country of publishing house
GB - UNITED KINGDOM
Number of pages
7
Pages from-to
3316-3322
UT code for WoS article
000320783300007
EID of the result in the Scopus database
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