Lanthanide-Porphyrin Hybrids: from Layered Structures to Metal-Organic Frameworks with Photophysical Properties

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F13%3A10141576" target="_blank" >RIV/00216208:11310/13:10141576 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/13:00392003 RIV/61388955:_____/13:00392003
Result on the web
<a href="http://dx.doi.org/10.1021/ic400182u" target="_blank" >http://dx.doi.org/10.1021/ic400182u</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ic400182u" target="_blank" >10.1021/ic400182u</a>

Result language
angličtina
Original language name
Lanthanide-Porphyrin Hybrids: from Layered Structures to Metal-Organic Frameworks with Photophysical Properties
Original language description
Rare-earth layered hydroxides with intercalated tetrasulfonated porphyrins and corresponding to the chemical formula Ln(2)(OH)(4.7)(Por)(0.33)center dot 2H(2)O (Ln = Eu3+, Tb3+; Por = 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS) and PdTPPS) have been prepared to investigate their photophysical properties. A slight variation of the synthetic procedure led to the metal-organic framework (MOF) assembled from a distorted octahedral oxometalate clusters [Eu-6(mu-O)(mu(3)-OH)(8)(H2O)(14)](8+). Thesesecondary building units (SBUs) are linked together by six distorted porphyrin units. During activation, the original SBU loses not only water molecules from the coordination sphere but also the central mu(6)-O atom. The loss of the central atom resultsin the distortion of the octahedral [Eu-6(mu(6)-O)(mu(3)-OH)(8)(H2O)(14)](8+) SBU into a trigonal antiprismatic [Eu-6(mu(3)-OH)(8)(H2O)](10+) SBU with two mu(3)-OH groups nearly in plane with the europium atoms and the reduction of pores
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GAP207%2F10%2F1447" target="_blank" >GAP207/10/1447: Photoactive hybrid materials</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)