Separation efficiency of dual-selector systems in capillary electrophoresis
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F14%3A10189962" target="_blank" >RIV/00216208:11310/14:10189962 - isvavai.cz</a>
Result on the web
<a href="http://ac.els-cdn.com/S0021967314000296/1-s2.0-S0021967314000296-main.pdf?_tid=e994d2bc-a561-11e4-80e7-00000aab0f6b&acdnat=1422280247_11ddaa9da1d9edef54a04e4866c0c8da" target="_blank" >http://ac.els-cdn.com/S0021967314000296/1-s2.0-S0021967314000296-main.pdf?_tid=e994d2bc-a561-11e4-80e7-00000aab0f6b&acdnat=1422280247_11ddaa9da1d9edef54a04e4866c0c8da</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.chroma.2014.01.006" target="_blank" >10.1016/j.chroma.2014.01.006</a>
Alternative languages
Result language
angličtina
Original language name
Separation efficiency of dual-selector systems in capillary electrophoresis
Original language description
We introduce an easy but highly descriptive model of separation efficiency of dual-selector systems in capillary electrophoresis.The model expresses effective mobilities of analytes in dual-selector mix-tures as a function of mixture composition and total concentration. The effective mobility follows the pattern familiar from single-selector systems, while complexation constant and mobility of the complex are replaced by the same but "overall" parameters and a total concentration of the mixture takes the role of a selector concentration. The overall parameters can be either calculated from the individual ones (an arbitrary mixture) or measured directly (a particular mixture). We inspected two model dual-selector systems consisting of heptakis(2,6-di-O-methyl)- -CD and -CD and of heptakis(2,6-di- O-methyl)- -CD and 6-O- -maltosyl- -CD, and ibuprofen and flurbiprofen as model analytes (pH 8.2, non-enantioselective separation).Adopting any optimization strategy typically used in single-se
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GPP206%2F12%2FP630" target="_blank" >GPP206/12/P630: Unified model and integrated computational tools for (dynamic) chiral separation in capillary zone electrophoresis</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Chromatography A
ISSN
0021-9673
e-ISSN
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Volume of the periodical
1330
Issue of the periodical within the volume
February 2014
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
7
Pages from-to
82-88
UT code for WoS article
000331688400011
EID of the result in the Scopus database
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