Gas-phase studies of copper catalyzed aerobic cross coupling of thiol esters and arylboronic acids

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F14%3A10209526" target="_blank" >RIV/00216208:11310/14:10209526 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/14:00427665
Result on the web
<a href="http://dx.doi.org/10.1002/poc.3262" target="_blank" >http://dx.doi.org/10.1002/poc.3262</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/poc.3262" target="_blank" >10.1002/poc.3262</a>

Result language
angličtina
Original language name
Gas-phase studies of copper catalyzed aerobic cross coupling of thiol esters and arylboronic acids
Original language description
Electrospray ionization/mass spectrometry (ESI-MS) is used to monitor a Cu-catalyzed aerobic cross-coupling reaction between thiol esters and arylboronic acids. The ESI spectra show the formation of Cu-complexes with the starting thiol ester 1 and the coupling product. The formation of an ionic complex at m/z 305 is observed, most likely occurring upon the elimination of a mixed anhydride from [(1)CuOAc](+). An online monitoring of the reaction using ESI-MS was carried out allowing calculation of rate constants and thermodynamic parameters (H-double dagger, S-double dagger, and G(double dagger)) for the title reaction.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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