Water-Soluble Manganese Inorganic Polymers: The Role of Carborane Clusters and Producing Large Structural Adjustments from Minor Molecular Changes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F14%3A10272212" target="_blank" >RIV/00216208:11310/14:10272212 - isvavai.cz</a>
Result on the web
<a href="http://onlinelibrary.wiley.com/doi/10.1002/chem.201403458/pdf" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/chem.201403458/pdf</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/chem.201403458" target="_blank" >10.1002/chem.201403458</a>

Result language
angličtina
Original language name
Water-Soluble Manganese Inorganic Polymers: The Role of Carborane Clusters and Producing Large Structural Adjustments from Minor Molecular Changes
Original language description
The reaction of two different carboranylcarboxylate ligands, 1-CH3-2-CO2H-1,2-closo-C2B10H10 or 1-CO2H-1,2- closo-C2B10H11, with MnCO3 in water leads to polymeric compounds 1a and 1b. Both compounds have been characterized by analytical and spectroscopictechniques. Additionally, electrochemical techniques have also been used for compound 1a. X-ray analysis revealed substantial differences between both compounds: whereas a six-coordinated MnII compound with water molecules bridging two MnII centers hasbeen observed for 1a, a square pyramidal geometry around each MnII ion with terminal water molecules coordinated to each MnII center has been found for 1b. The observed differences have been attributed to the existence of different substituents, CH3 or H, on one of the carbon atoms of the carboranylcarboxylate ligand. The reaction of 1a and 1b with coordinating solvents, such as ethers or Lewis bases, leads to the formation of new compounds with low (mononuclear 4a, 4b; dinuclear 3a, 3b;
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
—

Project
<a href="/en/project/GA14-14608S" target="_blank" >GA14-14608S: Preparation and characterization of novel polymeric metallacarborane-containing nanocomposites</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)