Synthesis, Crystal Structures, and Electrochemical Behavior of Fe-Ru Heterobimetallic Complexes with Bridged Metallocene Units
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F14%3A10281901" target="_blank" >RIV/00216208:11310/14:10281901 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/om500505n" target="_blank" >http://dx.doi.org/10.1021/om500505n</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om500505n" target="_blank" >10.1021/om500505n</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis, Crystal Structures, and Electrochemical Behavior of Fe-Ru Heterobimetallic Complexes with Bridged Metallocene Units
Original language description
A series of Fe-Ru complexes was prepared by reactions of (2-phenylethyl)ferrocene, (E)-(2-phenylethenyl)ferrocene, and (phenylethynyl)ferrocene with [Ru(eta(5)-C5R5)(MeCN)3][PF6] (R = H, Me) salts. These heterobimetallic complexes of the general formula[Fc-spacer-(eta(6)-C6H5)Ru(eta(5)-C5R5)][PF6] (Fc = ferrocenyl, spacer = CH2CH2 (4), CH=CH (5), CC (6)) were isolated as hexafluorophosphate salts and characterized by elemental analysis, NMR spectroscopy, and ESI MS. The structures of the complete series of [Fc-spacer-(eta(6)-C6H5)Ru(eta(5)-C5Me5)]Cl and of [FcC CRu(eta(6)-C6H5)(eta(5)-C5H5)][PF6] were determined by X-ray diffraction analysis. In addition, a cyclobutadiene complex [Ru(eta(5)-C5H5)(eta(4)-1,2-Fc2-3,4-Ph2C4)][PF6] (7[PF6]), obtained along with some unidentified alkyne oligomers and 6a[PF6] upon the treatment of 3 with [Ru(eta(5)-C5H5)(MeCN)3][PF6], was characterized similarly, including structure determination. Cyclic voltammetry measurements performed on the precursor F
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP207%2F11%2F0705" target="_blank" >GAP207/11/0705: Carborane-modified iron-arene complexes</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
33
Issue of the periodical within the volume
18
Country of publishing house
US - UNITED STATES
Number of pages
13
Pages from-to
5020-5032
UT code for WoS article
000342180800049
EID of the result in the Scopus database
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