Heterodinuclear Arene Ruthenium Complexes Containing a Glycine-Derived Phosphinoferrocene Carboxamide: Synthesis, Molecular Structure, Electrochemistry, and Catalytic Oxidation Activity in Aqueous Media
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10126168" target="_blank" >RIV/00216208:11310/12:10126168 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/om3002087" target="_blank" >http://dx.doi.org/10.1021/om3002087</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om3002087" target="_blank" >10.1021/om3002087</a>
Alternative languages
Result language
angličtina
Original language name
Heterodinuclear Arene Ruthenium Complexes Containing a Glycine-Derived Phosphinoferrocene Carboxamide: Synthesis, Molecular Structure, Electrochemistry, and Catalytic Oxidation Activity in Aqueous Media
Original language description
Three series of heterodinuclear ruthenium iron complexes have been synthesized from (eta(6)-arene)ruthenium dichloride dimers and phosphinoferrocene ligands containing glycine-based carboxamido substituents. The neutral complexes [(eta(6)-arene)RuCl2(Ph2PfcCONHCH2CO2Me-kappa P)] (4, arene = benzene (a), p-cymene (b), hexamethylbenzene (c); fc = ferrocene-1,1'-diyl) were obtained by the bridge cleavage reaction of [(eta(6)-arene)RuCl2](2) with Ph2PfcCONHCH2CO2Me (1) in chloroform solution. The complex [(eta(6)-p-cymene)RuCl2(Ph2PfcCONHCH2CONH2-kappa P)] (6b) was synthesized in the same way from Ph2PfcCONHCH2CONH2 (3); the preparation of [(eta(6)-p-cymene)RuCl2(Ph2PfcCONHCH2CO2H-kappa P)] (5b), featuring the ferrocene ligand in the free acid form (2), failed due to side reactions and isolation problems. The salts [(eta(6)-arene)RuCl(MeCN)(1-kappa P)][PF6] (7a-c) and [(eta(6)-arene)Ru(MeCN)2(1-kappa P)][PF6]2 (8a-c) were prepared from 1 and the acetonitrile precursors [(eta(6)-arene)RuCl(
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
31
Issue of the periodical within the volume
10
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
3985-3994
UT code for WoS article
000304385600022
EID of the result in the Scopus database
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