Half-sandwich Ru (II) complexes: Effect of ligands on aerobic oxidation of benzylamine

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F23%3A39920978" target="_blank" >RIV/00216275:25310/23:39920978 - isvavai.cz</a>
Result on the web
<a href="https://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.7284" target="_blank" >https://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.7284</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/aoc.7284" target="_blank" >10.1002/aoc.7284</a>

Result language
angličtina
Original language name
Half-sandwich Ru (II) complexes: Effect of ligands on aerobic oxidation of benzylamine
Original language description
In this study, we compared carbene and pyridine substituted ligands {3-Me-1-[2-(CH2CH2SPh)]-C7H4N2} (L1) and {2-[(2,6-iPr2-C6H3)N=CH]-6-(MeO)C5H3N}(L2) for synthesis of ionic C,S- and N,N-coordinated Ru (II) complexes [(kappa 2-L1)RuCl(eta 6-p-cymene)]+Cl- (1), [(kappa 2-L1)RuI(eta 6-p-cymene)]+I- (2), and [(kappa 2-L2)RuCl(eta 6-p-cymene)]+Cl- (3), respectively. Stannylene ligand [{2,6-(Me2NCH2)2C6H3}SnCl] (L3), as heavy carbene analog, was also used in this study to prepare neutral Sn-coordinated Ru (II) complex [(kappa 1-L3)RuCl2(eta 6-p-cymene)] (4). Finally, reaction of SnCl2 with 1, 3, and 4 was also studied to yield [(kappa 2-L1)RuCl(eta 6-p-cymene)]+[SnCl3]- (5), [(kappa 2-L2)RuCl(eta 6-p-cymene)]+[SnCl3]- (6), and [(kappa 1-L3)RuCl (SnCl3)(eta 6-p-cymene)] (7). The catalytic activity of 1-7 was tested on aerobic oxidation of benzylamine. The effect of different ligands L1-3 as well as the effect of the SnCl3- moiety is discussed. We use different donating systems for half-sandwich Ru (II) complexes to see the effect of ligands on aerobic oxidation of benzylamine.image
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA23-06548S" target="_blank" >GA23-06548S: Superhydrophobic materials based on heteroboroxines</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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