Role of the Trichlorostannyl Ligand in Tin-Ruthenium Arene Complexes: Experimental and Computational Studies
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F17%3A39911695" target="_blank" >RIV/00216275:25310/17:39911695 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/ejic.201700098" target="_blank" >http://dx.doi.org/10.1002/ejic.201700098</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201700098" target="_blank" >10.1002/ejic.201700098</a>
Alternative languages
Result language
angličtina
Original language name
Role of the Trichlorostannyl Ligand in Tin-Ruthenium Arene Complexes: Experimental and Computational Studies
Original language description
A set of neutral and ionic ruthenium arene trichlorostannyl complexes are reported herein. The tin(II)compounds (LSnCl)-Sn-1 {1; L-1 = [2-(CH2NEt2)-4,6-(tBu)(2)C6H2]-} and [(LSnCl)-Sn-2][SnCl3] {2; L-2 = 2,6-[(CH3)C=N(C6H3-2,6-iPr(2))(2)] C5H3N} showed a rather different reactivity towards the ruthenium complex [(eta(6-)cymene)RuCl](2)(eta-Cl)(2). As a consequence, the neutral complex [Ru(eta(6)-cymene)((LSnCl)-Sn-1)Cl-2] (4)and the ionic compound [(LSnCl)-Sn-2][Ru(eta(6)-cymene)(SnCl3)(2)Cl] (8)were isolated. The insertion reaction of 4 with SnCl2 provided the neutral trimetallic ruthenium complex [Ru(eta(6)-cymene)((LSnCl)-Sn-1)(SnCl3)Cl] (6). Analo-gous ruthenium complexes [Ru(eta(6)-cymene)((LPPh2)-P-3)Cl-2] (5)and [Ru(eta 6-cymene)((LPPh2)-P-3)(SnCl3)Cl] (7)containing the phosphane ligand L3PPh2 {3; L-3 = [2,6-iPr(2)-(C6H3)NH](-)} were also prepared to evaluate the donor-acceptor strength of the tin(II)-and phosphorus-containing ligands. The structural characterization and DFT calculations of the above-mentioned complexes suggest a strong influence of the [SnCl3](-)moiety on the Ru-E interaction (E = Sn, P). The influence of the trichlorostannyl ligand on the Ru-E interaction in the complexes 4-7 was further evaluated by means of a distortion/ interaction analysis.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
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Volume of the periodical
6
Issue of the periodical within the volume
9
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
1292-1300
UT code for WoS article
000395786700009
EID of the result in the Scopus database
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