Arene-Ruthenium Complexes with Phosphanylferrocenecarboxamides Bearing Polar Hydroxyalkyl Groups - Synthesis, Molecular Structure, and Catalytic Use in Redox Isomerizations of Allylic Alcohols to Carbonyl Compounds

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10126176" target="_blank" >RIV/00216208:11310/12:10126176 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/ejic.201200733" target="_blank" >http://dx.doi.org/10.1002/ejic.201200733</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201200733" target="_blank" >10.1002/ejic.201200733</a>

Result language
angličtina
Original language name
Arene-Ruthenium Complexes with Phosphanylferrocenecarboxamides Bearing Polar Hydroxyalkyl Groups - Synthesis, Molecular Structure, and Catalytic Use in Redox Isomerizations of Allylic Alcohols to Carbonyl Compounds
Original language description
Phosphanylferrocenecarboxamide Ph2PfcCONHCH2CH2OH (1, fc = ferrocene-1,1'-diyl) and its newly synthesized congeners, Ph2PfcCONHCH(CH2OH)2 (2) and Ph2PfcCONHC(CH2OH)3 (3), were converted to a series of (eta(6)-arene)ruthenium complexes [(eta(6)-arene)RuCl2(L-kappa P)] (5-7), where arene is benzene, p-cymene, and hexamethylbenzene and L = 1-3. All compounds were characterized by multinuclear NMR and IR spectroscopy, by mass spectrometry, and by elemental analysis. The molecular structures of 2, 3, 3O (a phosphane oxide resulting from the oxidation of 3), 5c.CH2Cl2, and 6c.Et2O were determined by single-crystal X-ray diffraction analysis. The ruthenium complexes were further evaluated as catalysts in the redox isomerization of allyl alcohols to carbonyl compounds. Complex [(eta(6)-p-cymene)RuCl2(1-kappa P)] (5b) proved to be a particularly attractive catalyst, being both readily available and catalytically active. Substrates with unsubstituted double bonds were cleanly isomerized with thi
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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