Adsorption of pentane isomers on metal-organic frameworks Cu-BTC and Fe-BTC

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10271593" target="_blank" >RIV/00216208:11310/15:10271593 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/15:00435102
Result on the web
<a href="http://ac.els-cdn.com/S0920586114004805/1-s2.0-S0920586114004805-main.pdf?_tid=cee76c2a-c8b3-11e4-828c-00000aacb360&acdnat=1426163712_3cba16ea3b63f26057d96e70f5cbf8e0" target="_blank" >http://ac.els-cdn.com/S0920586114004805/1-s2.0-S0920586114004805-main.pdf?_tid=cee76c2a-c8b3-11e4-828c-00000aacb360&acdnat=1426163712_3cba16ea3b63f26057d96e70f5cbf8e0</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.cattod.2014.07.003" target="_blank" >10.1016/j.cattod.2014.07.003</a>

Result language
angličtina
Original language name
Adsorption of pentane isomers on metal-organic frameworks Cu-BTC and Fe-BTC
Original language description
Adsorption isotherms of n-pentane, isopentane and cyclopentane on Cu-BTC and Fe-BTC metal-organic frameworks, measure in a temperatur range from 273 to 333 K, have been examined. For correlations, adsorption of nitrogen at 77 K and argon at 87 K has beenstudied as well. The analysis of adsorption isotherms was based on the calculation of differential distributions of the amount adsorbed with respect to the adsorption potential. It appears that the filling of Cu-BTC micropores with nitrogen occurs in two steps due to specific interaction of nitrogen molecules with open metal sites. In contrast to nitrogen, the filling of Cu-BTC micropores with argon takes place in one step. The micropores of Fe-BTC are filled with nitrogen and argon gradually in two featureless stages indicating the unordered porous structure. Adsorption isotherms of n -pentane, isopentane and cyclopentane display especially at 273 and 293 K a rectangular course with a long vertical part. This shape of C5 hydrocarbon i
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/GA14-07101S" target="_blank" >GA14-07101S: Combined Experimental and Theoretical Investigation of Catalytic Properties of Metal Organic Frameworks</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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