A new adsorption isotherm for C5 hydrocarbons on metal?organic framework Cu3(BTC)2

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F15%3A00441400" target="_blank" >RIV/61388955:_____/15:00441400 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1007/s10450-015-9653-0" target="_blank" >http://dx.doi.org/10.1007/s10450-015-9653-0</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s10450-015-9653-0" target="_blank" >10.1007/s10450-015-9653-0</a>

Result language

angličtina

Original language name

A new adsorption isotherm for C5 hydrocarbons on metal?organic framework Cu3(BTC)2

Original language description

A new equation describing isotherms of C5 hydrocarbons on metal?organic framework Cu3(BTC)2 in the temperature range from 273 to 333 K was developed. The isotherms of n-pentane, isopentane and cyclopentane on Cu3(BTC)2 belonging to the Type 5 according to the IUPAC classification are characterized by a long vertical part in the low pressure region. An analysis of isosteric adsorption heats has revealed that lateral interactions among pentane molecules adsorbed on Cu3(BTC)2 dominate over gas?solid interactions. Because there is no equation in the literature, which can be used for the description of isotherms under investigation, equation based on the Dubinin theory of S-shaped adsorption isotherms was developed. According to this theory each adsorbed molecule is a secondary center, which is capable to adsorb other molecules. The equation was suggested with respect to the leveling-off of the isotherms as at the end of the adsorption process the whole adsorption volume becomes filled with

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

<a href="/en/project/GA14-07101S" target="_blank" >GA14-07101S: Combined Experimental and Theoretical Investigation of Catalytic Properties of Metal Organic Frameworks</a><br>

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Adsorption-Journal of the International Adsorption Society

ISSN

0929-5607

e-ISSN

—

Volume of the periodical

21

Issue of the periodical within the volume

1-2

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

7

Pages from-to

99-105

UT code for WoS article

000349550800010

EID of the result in the Scopus database

2-s2.0-84921485996