The Synthesis and Structural Characterization of Polycyclic Derivatives of Cobalt Bis(dicarbollide)(1(-))

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10296268" target="_blank" >RIV/00216208:11310/15:10296268 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/15:00443361
Result on the web
<a href="http://dx.doi.org/10.1021/ic502450t" target="_blank" >http://dx.doi.org/10.1021/ic502450t</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ic502450t" target="_blank" >10.1021/ic502450t</a>

Result language
angličtina
Original language name
The Synthesis and Structural Characterization of Polycyclic Derivatives of Cobalt Bis(dicarbollide)(1(-))
Original language description
The cobalt bis(dicarbollide) anion [(1,2-C2B9H11)2-3,3'-Co]- (1-) is an important building block for the design of new biologically active compounds. Here we report the reactions of lithiated 1- with N-(?-bromoalkyl)phthalimides Br-(CH2)n-N(CO)2NC6H4 (where n=1 to 3) that give a number of new compounds substituted at dicarbollide carbon atom positions. For n=2 and 3, substitution of the cobalt bis(dicarbollide) anion is accompanied by cyclocondensation of the organic moieties to give polycyclic ring structures attached to the cage. Predominant products correspond to oxazolo[2,3-a]isoindol-5(9bH)-1,2,3-dihydro-9b-yl)-(1-cobalt(III) bis(1,2-dicarbollide)(1-) (2-) and 1-(2H-[1,3]-oxazino[2,3-a]isoindol-6(10bH)-1,3,4-dihydro-10b-yl)-(1-cobalt(III) bis(1,2-dicarbollide)(1-) (4-) ions with isoindolone functions containing either five- or six-membered lateral oxazine rings. Additionally, products (tetrahydro-2-benzo[4,5]furan-1(3H)-1-[3,3]-yl-)-1,1'-?-cobalt(III) bis(1,2-dicarbollide)(1-) (3-
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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