The Zwitterion [8,8-?-CH2O(CH3)-(1,2-C2B9H10)2-3,3-Co]0 as a Versatile Building Block To Introduce Cobalt Bis(Dicarbollide) Ion into Organic Molecules

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F12%3A10127569" target="_blank" >RIV/00216208:11310/12:10127569 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/12:00376238
Result on the web
<a href="http://dx.doi.org/10.1021/om200938n" target="_blank" >http://dx.doi.org/10.1021/om200938n</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om200938n" target="_blank" >10.1021/om200938n</a>

Result language
angličtina
Original language name
The Zwitterion [8,8-?-CH2O(CH3)-(1,2-C2B9H10)2-3,3-Co]0 as a Versatile Building Block To Introduce Cobalt Bis(Dicarbollide) Ion into Organic Molecules
Original language description
The synthesis of a new bridged [8,8-?-CH2O(CH3)-(1,2-C2B9H10)2-3,3-Co]0 derivative (2), arising from the acid-catalyzed reaction of cobalt bis(1,2-dicarbollide)(1) ion with formaldehyde, is reported. The proposed reaction path is supported by the isolation of side products including two zwitterionic compounds, the known bridged [8,8-?-(CH3O)-(1,2-C2B9H10)2-3,3-Co]0 derivative (3), the new zwitterion [(8-(CH3)2O-1,2-C2B9H10)-(1,2-C2B9H11)-3,3-Co]0 (4), and two anionic compounds-the known [(8,8-Cl2-1,2-C2B9H10)2-3,3-Co] and the newly characterized dimethoxy derivative [(8,8-(CH3O)2-1,2-C2B9H10)2-3,3-Co] of the cobalt bis(dicarbollide) ion. Compound 2 serves as a versatile building block for the construction of zwitterionic derivatives, as exemplified bythe synthesis of a series of compounds of general formulation [(8-X-CH2-1,2-C2B9H10)(8-CH3O-1,2-C2B9H10)-3,3-Co]0 (6). Compounds of type 6 bear organic end groups (X = NC5H5 (6a), C6H13NH2 (6b), 2-HOC2H4NH2 (6c), (C6H5)3P (6d)) adjacent t
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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