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Functionalized cobalt bis(dicarbollide) ions as selective extraction reagents for removal of M2+ and M3+ cations from nuclear waste, crystal and molecular structures of the [8,8 '-mu-CIP(O)(O)(2)(1,2-C2B9H10)(2)-3,3 '-Co]HN(C2H5)(3) and [8,8 '-mu-Et2NP(O

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F02%3A50023013" target="_blank" >RIV/61388980:_____/02:50023013 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Functionalized cobalt bis(dicarbollide) ions as selective extraction reagents for removal of M2+ and M3+ cations from nuclear waste, crystal and molecular structures of the [8,8 '-mu-CIP(O)(O)(2)(1,2-C2B9H10)(2)-3,3 '-Co]HN(C2H5)(3) and [8,8 '-mu-Et2NP(O

  • Original language description

    New reliable synthetic methods leading to derivatives of the closo-[(1,2-C2B9H11)(2)-3,3'-Co](-) (1) anion 1 with phosphorus containing substituents on the cage boron atoms have been successfully developed, starting from its 8-OH (2) and 8,8'-(OH)(2) (3)hydroxyderivatives. Reactions of 2 with either Cl3PO or PhCl2PO followed by hydrolysis gave 8-(HO)(2)PO-O- (4) and [(8-PhPO(OH) -O)- 1,2-C2B9H10)(1,2-C2B9H11)-3,3'-Co](-) (5) phosphorylated species, respectively. Analogous reactions Of Cl3PO with 3 provided a chlorine bearing bridged product [8,8'-mu-ClP(O)(O)(2) < (1,2-C2B9H10)(2)-3,3'-Co](-) (6) with surprisingly high hydrolytic stability. The anticipated anion [8,8'-mu-(HO)(O)-P(O)(2) < (1,2-C2B9H10)(2)-3,3'-Co](-) (7) with phosphoric acid as the bridging substituent was obtained after alkaline hydrolysis of compound 6. The related [8,8'-mu-Ph(O)P(O)(2) < (1,2-C2B9H10)(2)-3,3'-Co](-) (8) derivative was prepared by similar reaction of 3 with PhCl2PO and subsequent hydrolysis. Further

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2002

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Organometalic Chemistry

  • ISSN

    0022-328X

  • e-ISSN

  • Volume of the periodical

    657

  • Issue of the periodical within the volume

    1-2

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    12

  • Pages from-to

    59-70

  • UT code for WoS article

  • EID of the result in the Scopus database