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Syntheses of the B(8)-hydroxy- and B(8,8 )-dihydroxy-derivatives of the bis(1,2-dicarbollido)-3-cobalt(1-)ate ion by its reductive acetoxylation and hydroxylation: molecular structure of [8,8 - -CH3C(O)2(1,2-C2B9H10)2-3-Co]0 zwitterion determined by X-ra

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F02%3A50025007" target="_blank" >RIV/61388980:_____/02:50025007 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Syntheses of the B(8)-hydroxy- and B(8,8 )-dihydroxy-derivatives of the bis(1,2-dicarbollido)-3-cobalt(1-)ate ion by its reductive acetoxylation and hydroxylation: molecular structure of [8,8 - -CH3C(O)2(1,2-C2B9H10)2-3-Co]0 zwitterion determined by X-ra

  • Original language description

    Preparative routes to 8-hydroxy-bis(1,2-dicarbollido)-3-cobalt(1-)ate (2) and 8,8 -dihydroxy-bis(1,2-dicarbollido)-3-cobalt(1-)ate (3) ions are reported by the reductive acetoxylation of the parent bis(dicarbollido)cobaltate ion (1) followed by hydrolysis of the intermediates. The essential reagent is acetic anhydride, and strong acids are required as catalysts. For the hydroxyderivative ion 2 the simultaneous presence of acetic acid brings benefit, whereas it is detrimental for the formation of the dihydroxyderivative 3. Reaction intermediate leading to the dihydroxy derivative is the already reported [8,8 - -CH3C(O)2(1,2-C2B9H10)2-3-Co]0 zwitterion. This compound was adequately characterised for the first time and its molecular structure as determined by X-ray diffraction analysis is presented. Both B-hydroxylated bis(dicarbollido)-ions can be alternatively obtained on the direct hydroxylation of the parent ion by hot 60-80 sulphuric acid. Optimised synthetic procedures and the main

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2002

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Organometallic Chemistry

  • ISSN

    0022-328X

  • e-ISSN

  • Volume of the periodical

    649

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    10

  • Pages from-to

    181-190

  • UT code for WoS article

  • EID of the result in the Scopus database