Single crystals of guanidinium zinc sulfate, [C(NH2)(3)](2)Zn(SO4)(2) - growth, structure, vibrational spectroscopy and stimulated Raman scattering
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10313141" target="_blank" >RIV/00216208:11310/15:10313141 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1515/zkri-2015-1839" target="_blank" >http://dx.doi.org/10.1515/zkri-2015-1839</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1515/zkri-2015-1839" target="_blank" >10.1515/zkri-2015-1839</a>
Alternative languages
Result language
angličtina
Original language name
Single crystals of guanidinium zinc sulfate, [C(NH2)(3)](2)Zn(SO4)(2) - growth, structure, vibrational spectroscopy and stimulated Raman scattering
Original language description
Large single crystals of the tetragonal (space group I (4) over bar 2d) guanidinium zinc sulfate, [C(NH2)(3)](2)Zn(SO4)(2), were grown and the crystal structure was redetermined. Vibrational spectra obtained by Raman and IR investigations are presented,together with an assignment of the observed vibration modes. Precise refractive index data in the wavelength range from 0.365 to 1.083 mu m are given. [C(NH2)(3)](2)Zn(SO4)(2) is introduced as a new stimulated Raman scattering (SRS)-active crystal with three SRS-active vibration modes with omega(SRS1) approximate to 985 cm(-1), omega(SRS2) approximate to 3390 cm(-1) and omega(SRS3) approximate to 1015 cm(-1). They allow for the generation of broadband nonlinear emission via chi(3)-(SRS and Raman-inducedfour wave mixing, RFWM) as well as cascaded chi(2)<->chi(3)-processes.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA14-05506S" target="_blank" >GA14-05506S: Crystal engineering of novel molecular crystals for non-linear optics</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Zeitschrift für Kristallographie - Crystalline Materials
ISSN
2194-4946
e-ISSN
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Volume of the periodical
230
Issue of the periodical within the volume
11
Country of publishing house
DE - GERMANY
Number of pages
11
Pages from-to
639-649
UT code for WoS article
000364317300003
EID of the result in the Scopus database
2-s2.0-84946882152