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Foaming of polysiloxane resins with ethanol: A new route to pyrolytic macrocellular SiOC foams

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10315034" target="_blank" >RIV/00216208:11310/15:10315034 - isvavai.cz</a>

  • Alternative codes found

    RIV/68081723:_____/15:00447628 RIV/61389013:_____/15:00447628 RIV/67985891:_____/15:00447628

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.ceramint.2015.07.151" target="_blank" >http://dx.doi.org/10.1016/j.ceramint.2015.07.151</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.ceramint.2015.07.151" target="_blank" >10.1016/j.ceramint.2015.07.151</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Foaming of polysiloxane resins with ethanol: A new route to pyrolytic macrocellular SiOC foams

  • Original language description

    Polysiloxane foams as precursors to silicon oxycarbide (SiOC) foams were prepared via simultaneous cure and foaming of liquid methylsiloxane resins, using the relatively environment-friendly ethanol as blowing additive of the boiling-solvent-type, and concentrated aqueous ammonia as catalyst. In order to achieve foam regularity, siloxane-based surfactants were added, and bubble nucleation by mechanical stirring was performed. The precursor foams were subsequently pyrolysed in nitrogen at 1000 degrees C,yielding SiOC foams as end products. The properties of the latter were fine-tuned during the foaming of the precursors, by the amount of added ethanol and by the time of mechanical stirring prior to foaming. The so-obtained SiOC foams displayed densities of 0.17-0.42 g/cm(-3), corresponding to macro-porosities of 91-79%, compressive strength of 1-6 MPa, and elastic moduli of 0.2-1.6 GPa.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    JI - Composite materials

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP107%2F12%2F2445" target="_blank" >GAP107/12/2445: SiOC ceramic foam from pyrolyzed polymer precursor as a core of thermally stable composite sandwich structures</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Ceramics International

  • ISSN

    0272-8842

  • e-ISSN

  • Volume of the periodical

    41

  • Issue of the periodical within the volume

    10

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    11

  • Pages from-to

    13561-13571

  • UT code for WoS article

    000362860900129

  • EID of the result in the Scopus database

    2-s2.0-84939515640