Classical Amphiphilic Behavior of Nonclassical Amphiphiles: A Comparison of Metallacarborane Self-Assembly with SDS Micellization
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F15%3A10319247" target="_blank" >RIV/00216208:11310/15:10319247 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/anie.201506545" target="_blank" >http://dx.doi.org/10.1002/anie.201506545</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.201506545" target="_blank" >10.1002/anie.201506545</a>
Alternative languages
Result language
angličtina
Original language name
Classical Amphiphilic Behavior of Nonclassical Amphiphiles: A Comparison of Metallacarborane Self-Assembly with SDS Micellization
Original language description
The self-assembly of metallacarboranes, a peculiar family of compounds exhibiting surface activity and resembling molecular-scale Pickering stabilizers, has been investigated by comparison to the micellization of sodium dodecylsulfate (SDS). These studies have shown that molecules without classical amphiphilic topology but with an inherent amphiphilic nature can behave similarly to classical surfactants. As shown by NMR techniques, the self-assembly of both metallacarboranes and SDS obey a closed association model. However, the aggregation of metallacarboranes is found to be enthalpy-driven, which is very unusual for classical surfactants. Possible explanations of this fact are outlined.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA14-14608S" target="_blank" >GA14-14608S: Preparation and characterization of novel polymeric metallacarborane-containing nanocomposites</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Angewandte Chemie - International Edition
ISSN
1433-7851
e-ISSN
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Volume of the periodical
54
Issue of the periodical within the volume
47
Country of publishing house
DE - GERMANY
Number of pages
5
Pages from-to
14113-14117
UT code for WoS article
000367722500050
EID of the result in the Scopus database
2-s2.0-84954406347