Gas-phase study of metal complexes with redox-active ligands

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F16%3A10328140" target="_blank" >RIV/00216208:11310/16:10328140 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ijms.2016.07.010" target="_blank" >http://dx.doi.org/10.1016/j.ijms.2016.07.010</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ijms.2016.07.010" target="_blank" >10.1016/j.ijms.2016.07.010</a>

Result language
angličtina
Original language name
Gas-phase study of metal complexes with redox-active ligands
Original language description
Singly charged complexes of copper, silver, sodium, and zinc with redox-active ligands (catechol, maltol, and phenanthraquinone) were studied by mass spectrometry, infrared multiphoton dissociation (IRMPD) spectroscopy, and density functional theory calculations. The redox processes in copper complexes were evaluated based on a comparison with complexes bearing a non-redox active metal and by using the C-O stretching mode as a redox marker. We have detected changes in electron distribution in copper complexes with phenanthraquinone and maltol. It led to a partial reduction of the phenanthraquinone ligands on one hand and to the oxidation of maltol on the other.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA14-20077S" target="_blank" >GA14-20077S: Non-heme iron catalysts: Investigation of reaction mechanisms</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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