Catalytic Activity of Gold(I) Complexes with Hemilabile P,N Ligands
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F17%3A10338451" target="_blank" >RIV/00216208:11310/17:10338451 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/cplu.201600562" target="_blank" >http://dx.doi.org/10.1002/cplu.201600562</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cplu.201600562" target="_blank" >10.1002/cplu.201600562</a>
Alternative languages
Result language
angličtina
Original language name
Catalytic Activity of Gold(I) Complexes with Hemilabile P,N Ligands
Original language description
Two new cationic dinuclear gold(I) complexes, [Au2{mu(P,N)-5}2]X2, in which X = NTf2 (7; Tf= trifluoromethanesulfonate) or SbF6 (8) and 2-(diphenylphosphanyl) benzonitrile (5) is a P, Nbridging donor, have been synthesized and structurally characterized. These air-stable species and their dimeric and polymeric analogues possessing 1'-(diphenylphosphanyl)-1-cyanoferrocene (1) as the bridging ligand, [Au2{mu(P,N)-1}2](NTf2)2 and [Au{m(P, N)-1}]n[SbF6]n, were used as precatalysts in various Aumediated C-C and C-O bond-forming reactions. The reactivity of these complexes revealed the hemilabile nature of their P, N ligands. In the series of tested precatalysts, complex 8 exerted particularly high catalytic activity at low Au loading, even in reactions that usually require high amounts of gold catalyst to proceed efficiently under standard reaction conditions.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA13-08890S" target="_blank" >GA13-08890S: Polar ferrocene amidophosphine ligands for catalytic applications</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemPlusChem
ISSN
2192-6506
e-ISSN
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Volume of the periodical
82
Issue of the periodical within the volume
3
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
442-448
UT code for WoS article
000398034000016
EID of the result in the Scopus database
2-s2.0-85010469795