Silver(I) complexes with 1'-(diphenylphosphino)-1-cyanoferrocene and nitrite or nitrate supporting ligands

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F17%3A10364723" target="_blank" >RIV/00216208:11310/17:10364723 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.inoche.2017.08.033" target="_blank" >https://doi.org/10.1016/j.inoche.2017.08.033</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.inoche.2017.08.033" target="_blank" >10.1016/j.inoche.2017.08.033</a>

Result language
angličtina
Original language name
Silver(I) complexes with 1'-(diphenylphosphino)-1-cyanoferrocene and nitrite or nitrate supporting ligands
Original language description
The reactions of 1'-(diphenylphosphino)-1-cyanoferrocene (1) and silver(I) salts with common oxoanions, viz. AgNO3, AgNO2 and Ag2SO4, led to defined products only in the case of AgNO3 and AgNO2. Whereas the reactions involving silver(I) nitrate produced the phosphine complex [Ag(NO3-kappa O-2,O')(1-kappa P)(2)] (2) irrespective of the metal-to-ligand ratio, those with AgNO2 gave rise to the coordination polymer [Ag{mu(P,N)-1}(NO2-kappa O-2,O')](n) (3) and the discrete monosilver complex [Ag(NO2-kappa O,O')(1-kappa P)(2)] (4) at the Ag:1 molar ratios 1:1 and 1:2, respectively. Compounds 2-4 were structural characterized by spectroscopic methods and by single-crystal X-ray diffraction analysis.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA13-08890S" target="_blank" >GA13-08890S: Polar ferrocene amidophosphine ligands for catalytic applications</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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