X-ray characterization of triphenylphosphine-gold(I) olefin pi-complexes and the revision of their stability in solution
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F17%3A10367965" target="_blank" >RIV/00216208:11310/17:10367965 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.jorganchem.2017.07.011" target="_blank" >https://doi.org/10.1016/j.jorganchem.2017.07.011</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jorganchem.2017.07.011" target="_blank" >10.1016/j.jorganchem.2017.07.011</a>
Alternative languages
Result language
angličtina
Original language name
X-ray characterization of triphenylphosphine-gold(I) olefin pi-complexes and the revision of their stability in solution
Original language description
A large number of cationic Au(I) pi-complexes have been reported in the literature. However, a single Xray structure of genuine [Au(PPh3)(hydrocarbon)](+) pi-complex without any additional stabilization has not been published so far. We present herein isolation and X-ray characterization of several complexes of this type. Also, we show that these pi-complexes are more stable than previously reported and we investigate different modes of activation of the [Au(PPh3)] Cl precatalyst on their stability in solution.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Organometallic Chemistry
ISSN
0022-328X
e-ISSN
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Volume of the periodical
848
Issue of the periodical within the volume
October
Country of publishing house
CH - SWITZERLAND
Number of pages
4
Pages from-to
114-117
UT code for WoS article
000410565800007
EID of the result in the Scopus database
2-s2.0-85026455093