Reactivity of Copper(III)-Oxo Complexes in the Gas Phase
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F17%3A10370932" target="_blank" >RIV/00216208:11310/17:10370932 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1002/cphc.201700490" target="_blank" >https://doi.org/10.1002/cphc.201700490</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cphc.201700490" target="_blank" >10.1002/cphc.201700490</a>
Alternative languages
Result language
angličtina
Original language name
Reactivity of Copper(III)-Oxo Complexes in the Gas Phase
Original language description
An efficient way to generate [(L)CuO](+) complexes with a number of monodentate and bidentate ligands (L) from their [(L)Cu(ClO3)](+) precursors by electrospray ionization was herein explored. Further, we studied [(L)CuO](+) with L = 9,10-phenanthraquinone, 1,10- phenanthroline, and acetonitrile in detail. The signature of these terminal copper-oxo complexes was found to be elimination of the oxygen atom upon collisional activation. We investigated and compared their reactions with water, ethane, ethylene, and 1,4-cyclohexadiene. The [(MeCN)CuO](+) complex oxidized water and performed C-H activation and hydroxylation of ethane. The complexes with bidentate ligands did not react with water and oxidized only larger hydrocarbons. All the investigated complexes showed comparable reactivities in the oxygen-transfer reaction with ethylene.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GA14-20077S" target="_blank" >GA14-20077S: Non-heme iron catalysts: Investigation of reaction mechanisms</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemphyschem : a European journal of chemical physics and physical chemistry
ISSN
1439-4235
e-ISSN
—
Volume of the periodical
18
Issue of the periodical within the volume
16
Country of publishing house
DE - GERMANY
Number of pages
8
Pages from-to
2217-2224
UT code for WoS article
000407952400012
EID of the result in the Scopus database
2-s2.0-85021353386