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Carbon Electrodes in Electrochemical Analysis of Biomolecules and Bioactive Substances: Roles of Surface Structures and Chemical Groups

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F18%3A10392223" target="_blank" >RIV/00216208:11310/18:10392223 - isvavai.cz</a>

  • Alternative codes found

    RIV/68081707:_____/18:00535968

  • Result on the web

    <a href="https://www.sciencedirect.com/book/9780128138557/nanotechnology-and-biosensors#book-info" target="_blank" >https://www.sciencedirect.com/book/9780128138557/nanotechnology-and-biosensors#book-info</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/B978-0-12-813855-7.00003-9" target="_blank" >10.1016/B978-0-12-813855-7.00003-9</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Carbon Electrodes in Electrochemical Analysis of Biomolecules and Bioactive Substances: Roles of Surface Structures and Chemical Groups

  • Original language description

    In this chapter we focus on the properties of graphitic carbon and boron-doped diamond (BDD) electrodes from the point of view of surface micro- and nanostructures, chemistry of surface termination, effects of these characteristics on electron transfer and adsorption characteristics of the electrodes. Their properties are discussed in relation to electrochemical responses measured for typical groups of analytes, such as nucleic acid and protein constituents or other electroactive compounds. In general, basal planes of graphitic materials are sites of preferential adsorption of organic compounds while the edge planes and defects are sites of fast electron transfer for a number of analytes. At the BDD, fast electron transfer kinetics is observed particularly at hydrogenated and polished surfaces. Surface termination with oxygenous groups causes the electron transfer rate to decrease and renders the carbon surface hydrophilic properties, manifested in decreased adsorption of hydrophobic molecules and involvement of coulombic forces and hydrogen bonds in interactions of relevant analytes with the electrode surfaces. Examples of applications in the area of electroanalysis of biomolecules and their components are briefly discussed.

  • Czech name

  • Czech description

Classification

  • Type

    C - Chapter in a specialist book

  • CEP classification

  • OECD FORD branch

    10406 - Analytical chemistry

Result continuities

  • Project

    <a href="/en/project/GBP206%2F12%2FG151" target="_blank" >GBP206/12/G151: Center of novel approaches to bioanalysis and molecular diagnostics</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Book/collection name

    Nanotechnology and Biosensors

  • ISBN

    978-0-12-813855-7

  • Number of pages of the result

    61

  • Pages from-to

    51-111

  • Number of pages of the book

    470

  • Publisher name

    Elsevier

  • Place of publication

    Amsterodam

  • UT code for WoS chapter