Carbon Electrodes in Electrochemical Analysis of Biomolecules and Bioactive Substances: Roles of Surface Structures and Chemical Groups
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F18%3A10392223" target="_blank" >RIV/00216208:11310/18:10392223 - isvavai.cz</a>
Alternative codes found
RIV/68081707:_____/18:00535968
Result on the web
<a href="https://www.sciencedirect.com/book/9780128138557/nanotechnology-and-biosensors#book-info" target="_blank" >https://www.sciencedirect.com/book/9780128138557/nanotechnology-and-biosensors#book-info</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/B978-0-12-813855-7.00003-9" target="_blank" >10.1016/B978-0-12-813855-7.00003-9</a>
Alternative languages
Result language
angličtina
Original language name
Carbon Electrodes in Electrochemical Analysis of Biomolecules and Bioactive Substances: Roles of Surface Structures and Chemical Groups
Original language description
In this chapter we focus on the properties of graphitic carbon and boron-doped diamond (BDD) electrodes from the point of view of surface micro- and nanostructures, chemistry of surface termination, effects of these characteristics on electron transfer and adsorption characteristics of the electrodes. Their properties are discussed in relation to electrochemical responses measured for typical groups of analytes, such as nucleic acid and protein constituents or other electroactive compounds. In general, basal planes of graphitic materials are sites of preferential adsorption of organic compounds while the edge planes and defects are sites of fast electron transfer for a number of analytes. At the BDD, fast electron transfer kinetics is observed particularly at hydrogenated and polished surfaces. Surface termination with oxygenous groups causes the electron transfer rate to decrease and renders the carbon surface hydrophilic properties, manifested in decreased adsorption of hydrophobic molecules and involvement of coulombic forces and hydrogen bonds in interactions of relevant analytes with the electrode surfaces. Examples of applications in the area of electroanalysis of biomolecules and their components are briefly discussed.
Czech name
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Czech description
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Classification
Type
C - Chapter in a specialist book
CEP classification
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OECD FORD branch
10406 - Analytical chemistry
Result continuities
Project
<a href="/en/project/GBP206%2F12%2FG151" target="_blank" >GBP206/12/G151: Center of novel approaches to bioanalysis and molecular diagnostics</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Book/collection name
Nanotechnology and Biosensors
ISBN
978-0-12-813855-7
Number of pages of the result
61
Pages from-to
51-111
Number of pages of the book
470
Publisher name
Elsevier
Place of publication
Amsterodam
UT code for WoS chapter
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