Silver(I) pyridylphosphonates - synthesis, structure, stability and light-insensitivity investigation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F19%3A10393761" target="_blank" >RIV/00216208:11310/19:10393761 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=5qj~9Vigf_" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=5qj~9Vigf_</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c8ra10136a" target="_blank" >10.1039/c8ra10136a</a>
Alternative languages
Result language
angličtina
Original language name
Silver(I) pyridylphosphonates - synthesis, structure, stability and light-insensitivity investigation
Original language description
Two silver(I) complexes, {[Ag-7(2-pypo)(3)(NO3)]}(n) (1) and [Ag(3-pypoH)(3-pypoH(2))] (2) (pypoH(2) - pyridylphosphonic acid) were prepared and characterized by relevant methods in the solid state (elemental, spectral, thermal and structural analysis). Typical argentophilic interactions were observed in complex 1. The synthesized Ag(I) complexes were tested toward reduction to silver(0) using short wavelength UV-radiation and they revealed remarkable light-insensitivity in comparison to silver nitrate. SEM experiments were performed to observe the reduction of silver after the UV-light exposure of the samples. Light-insensitivity with the examined thermal stability and insolubility of the new complexes demonstrates their high potential to be used as light-insensitive materials in medical devices.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
RSC Advances
ISSN
2046-2069
e-ISSN
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Volume of the periodical
9
Issue of the periodical within the volume
3
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
1570-1575
UT code for WoS article
000457292800045
EID of the result in the Scopus database
2-s2.0-85060163905