Synthesis, characterization, crystal structure and antibacterial activity of new sulfur-bridged dinuclear silver(I) thiosemicarbazone complex [Ag2(PPh3)2(?-S-Brcatsc)2(?1-S-Brcatsc)2](NO3)2.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00448370" target="_blank" >RIV/68378271:_____/15:00448370 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ica.2015.01.043" target="_blank" >http://dx.doi.org/10.1016/j.ica.2015.01.043</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2015.01.043" target="_blank" >10.1016/j.ica.2015.01.043</a>

Result language
angličtina
Original language name
Synthesis, characterization, crystal structure and antibacterial activity of new sulfur-bridged dinuclear silver(I) thiosemicarbazone complex [Ag2(PPh3)2(?-S-Brcatsc)2(?1-S-Brcatsc)2](NO3)2.
Original language description
In this paper, a new sulfur-bridged dinuclear silver(I) thiosemicarbazone complex [Ag2(PPh3)2(?-S-Brcatsc)2(?1-S-Brcatsc)2](NO3)2 was synthesized by the reaction of silver(I) nitrate with 2-bromo-3-phenylpropenalthiosemicarbazone (Brcatsc) in the presence of triphenylphosphine (PPh3) (1:1:2 M ratio). The complex was characterized by elemental analyses (CHNS), FT-IR and 1H & 13C NMR spectroscopy and structurally characterized by single-crystal X-ray diffraction analysis. X-ray result showed that the Brcatsc acted as a neutral ligand coordinated to the silver(I) ion in two different bonding modes (?-S-and ?1-S-). The Ag...Ag separation in the Ag(?-S)2Ag core is 3.699(2) A.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Project
<a href="/en/project/GA14-03276S" target="_blank" >GA14-03276S: Aspherical effects and their application for statistically correct crystal structure analysis</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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