Square-planar nickel(II) O,O'-dialkyldithiophoshato complexes with triphenylphospine of the type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F04%3A00002292" target="_blank" >RIV/61989592:15310/04:00002292 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/04:00009884
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Square-planar nickel(II) O,O'-dialkyldithiophoshato complexes with triphenylphospine of the type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS)
Original language description
A series of new [NiX(S2P{O-c-Hex}2)(PPh3)] (X = Cl, Br, I and NCS) (1-4) and [Ni(NCS)(S2P{OR}2)(PPh3)] [R = n-Pr (5), i-Pr (6)] complexes has been synthesized and characterized by elemental analyses, f.i.r., i.r., u.v.-vis., H1, C13{H1} n.m. spectra, magnetochemical and conducivity measurements. A single crystal X-ray analysis of [Ni(NCS)(S2P{O-n-Pr}2(PPh3)] (5) reveals the molecular structure of the complex and confirms a square-planar geometry around the central atom of nickel with the NCS anion coordinated via the nitrogen atom.
Czech name
Čtvercové nikelnaté O,O'-dialkyldithiofosfátové komplexy s trifenylfosfinem typu [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I a NCS)
Czech description
Byly syntetizovány a charakterizovány čtvercové nikelnaté O,O'-dialkyldithiofosfátové komplexy s trifenylfosfinem typu [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I a NCS).
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Transition Metal Chemistry
ISSN
0340-4285
e-ISSN
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Volume of the periodical
29
Issue of the periodical within the volume
4
Country of publishing house
GB - UNITED KINGDOM
Number of pages
6
Pages from-to
352-357
UT code for WoS article
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EID of the result in the Scopus database
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