Nickel(II) N-Benzyl-N-methyldithiocarbamato Complexes as Precursors for the Preparation of Graphite Oxidation Accelerators

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15310%2F10%3A10213230" target="_blank" >RIV/61989592:15310/10:10213230 - isvavai.cz</a>

Alternative codes found

RIV/61988987:17310/10:A1100YJK

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Nickel(II) N-Benzyl-N-methyldithiocarbamato Complexes as Precursors for the Preparation of Graphite Oxidation Accelerators

Original language description

The nickel(II) N-benzyl-N-methyldithiocarbantato (BzMedtc) complexes [Ni(BzMedtc)(PPh3)Cl] (1), [Ni(BzMedtc)(PPh3)Br] (2), [Ni(BzMedtc)(PPh3)I] (3), and [Ni(BzMedtc)(PPh3)(NCS)] (4) were synthesized. Subsequently, complex 1 was used for the preparation of [Ni(BzMedtc)(PPh3)(2)]ClO4 (5), [Ni(BzMedtc)(PPh3)(2)]BPh4 (6), and [Ni(BzMedtc)(PPh3)(2)]PF6 (7). The molecular structures of 4 and 5.H2O were determined by a single-crystal X-ray analysis. In all cases, the Ni-II atom is tetracoordinated in a distorted square-planar arrangement with the S2PX, and S2P2 donor set, respectively. The catalytic influence of selected complexes 1, 3, 5, and 6 on graphite oxidation was studied.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2010

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

ISSN

0044-2313

e-ISSN

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Volume of the periodical

636

Issue of the periodical within the volume

8

Country of publishing house

DE - GERMANY

Number of pages

8

Pages from-to

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UT code for WoS article

000280659500023

EID of the result in the Scopus database

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