Square-Planar Nickel(II) O,O?-Dialkyldithiophosphato Complexes with Triphenylphosphine of the Type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389030%3A_____%2F04%3A00000298" target="_blank" >RIV/61389030:_____/04:00000298 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Square-Planar Nickel(II) O,O?-Dialkyldithiophosphato Complexes with Triphenylphosphine of the Type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS)
Original language description
A series of new [NiX(S2P{O-c-Hex}2)(PPh3)](X = Cl?, Br?, I? and NCS?)(1)?(4) and [Ni(NCS)(S2P{OR}2)(PPh3)][R =n-Pr (5), i-Pr (6)] complexes has been synthesized and characterized by elemental analyses, f. i. r., i. r., u.v.?vis., 1H-, 13C{1H}- and 31P{1H}-n.m.r. spectra, magnetochemical and conductivity measurements. A single crystal X-ray analysis of [Ni(NCS)(S2P{O-n-Pr}2)(PPh3)](5) reveals the molecular structure of the complex and confirms a square-planar geometry around the central atom of nickel with the NCS anion coordinated via the nitrogen atom.
Czech name
Square-planární nikl(II) O,O '-dialkyldithiophosphato komplexy s triphenylphosphinem typu [NiX(S2P{OR}(2))(PPh3)] (X = Cl, Br, I and NCS)
Czech description
Square-planární nikl(II) O,O '-dialkyldithiophosphato komplexy s triphenylphosphinem typu [NiX(S2P{OR}(2))(PPh3)] (X = Cl, Br, I and NCS)

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/GA203%2F02%2F0436" target="_blank" >GA203/02/0436: Application of Crystallographic Databases in Scientific Practice</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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