O,O '-Dialkyldithiophosphato and O-alkyldithiophosphato nickel(II) complexes with bidentate P-donor ligands
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15410%2F03%3A00001518" target="_blank" >RIV/61989592:15410/03:00001518 - isvavai.cz</a>
Alternative codes found
RIV/61389030:_____/03:56033118 RIV/00216224:14330/03:00008559
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
O,O '-Dialkyldithiophosphato and O-alkyldithiophosphato nickel(II) complexes with bidentate P-donor ligands
Original language description
The following complexes, having the general formula [Ni(S2P{O}OR)(P-P)] {R = Et (1), i-Pr (2), P-P = dppe; R = Et (3), PP = 1,4-bis(diphenylphosphino)butane (dppb)}, [Ni(S2P{OR}(2))(P-P)]X {R = i-Pr (4), Et (5), P-P = 1,2-bis(diphenylphosphino)ethane (dppe); R =. Et, P-P = 1,1-bis(diphenylphosphino)methane (dppm) (6); X = ClO4-} and [Ni(S2P{OR}(2))(dppe)X] {R = i-Pr, X = NCS- (7); R = Et, X = Br- (8)}, have been synthesized. All the compounds have been characterized by elemental analyses, IR, UV-Vis, and P-31{H} NMR spectral studies, magnetic and conductivity measurements. Single crystal X-ray analysis revealed the molecular structures of [Ni(S2P{O}OEt)(dppe)] (1), [Ni(S2P{O}OEt)(dppE)](EtOH)-Et-. (3) and [Ni(S2P{OEt}(2))(dppe)]ClO4 (5), and confirmeda square-planar geometry around the nickel atoms. We have reason to believe that the coordination geometry in [Ni(S2P{OEt}(2))(dppe)Br](H2O)-H-. (8) is probably tetrahedral with monodentate coordinated (S2P{OEt}(2)) monoanion. (C) 2003 El
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F02%2F0436" target="_blank" >GA203/02/0436: Application of Crystallographic Databases in Scientific Practice</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polyhedron
ISSN
0277-5387
e-ISSN
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Volume of the periodical
22
Issue of the periodical within the volume
10
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
1341-1348
UT code for WoS article
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EID of the result in the Scopus database
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