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O,O '-Dialkyldithiophosphato and O-alkyldithiophosphato nickel(II) complexes with bidentate P-donor ligands

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15410%2F03%3A00001518" target="_blank" >RIV/61989592:15410/03:00001518 - isvavai.cz</a>

  • Alternative codes found

    RIV/61389030:_____/03:56033118 RIV/00216224:14330/03:00008559

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    O,O '-Dialkyldithiophosphato and O-alkyldithiophosphato nickel(II) complexes with bidentate P-donor ligands

  • Original language description

    The following complexes, having the general formula [Ni(S2P{O}OR)(P-P)] {R = Et (1), i-Pr (2), P-P = dppe; R = Et (3), PP = 1,4-bis(diphenylphosphino)butane (dppb)}, [Ni(S2P{OR}(2))(P-P)]X {R = i-Pr (4), Et (5), P-P = 1,2-bis(diphenylphosphino)ethane (dppe); R =. Et, P-P = 1,1-bis(diphenylphosphino)methane (dppm) (6); X = ClO4-} and [Ni(S2P{OR}(2))(dppe)X] {R = i-Pr, X = NCS- (7); R = Et, X = Br- (8)}, have been synthesized. All the compounds have been characterized by elemental analyses, IR, UV-Vis, and P-31{H} NMR spectral studies, magnetic and conductivity measurements. Single crystal X-ray analysis revealed the molecular structures of [Ni(S2P{O}OEt)(dppe)] (1), [Ni(S2P{O}OEt)(dppE)](EtOH)-Et-. (3) and [Ni(S2P{OEt}(2))(dppe)]ClO4 (5), and confirmeda square-planar geometry around the nickel atoms. We have reason to believe that the coordination geometry in [Ni(S2P{OEt}(2))(dppe)Br](H2O)-H-. (8) is probably tetrahedral with monodentate coordinated (S2P{OEt}(2)) monoanion. (C) 2003 El

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA203%2F02%2F0436" target="_blank" >GA203/02/0436: Application of Crystallographic Databases in Scientific Practice</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2003

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polyhedron

  • ISSN

    0277-5387

  • e-ISSN

  • Volume of the periodical

    22

  • Issue of the periodical within the volume

    10

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    8

  • Pages from-to

    1341-1348

  • UT code for WoS article

  • EID of the result in the Scopus database