Remarkably enhanced ferromagnetism in a super-exchange governed Cr2Ge2Te6 monolayer via molecular adsorption
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F19%3A10403400" target="_blank" >RIV/00216208:11310/19:10403400 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=n_l032XLE3" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=n_l032XLE3</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c8tc05530k" target="_blank" >10.1039/c8tc05530k</a>
Alternative languages
Result language
angličtina
Original language name
Remarkably enhanced ferromagnetism in a super-exchange governed Cr2Ge2Te6 monolayer via molecular adsorption
Original language description
Manipulation of the electronic properties of 2D materials with molecular adsorption has been widely reported in the past decade. However, the impact of adsorption of molecules on the magnetism of intrinsic 2D magnets is not yet sufficiently understood. Inspired by the recent discovery of intrinsic 2D ferromagnetism in atomically thin Cr2Ge2Te6 and CrI3 crystals, in this investigation, the adsorption of gas molecules including CO, CO2, H2O, N-2, NH3, NO, NO2, O-2 and SO2 on the basal plane of a Cr2Ge2Te6 (CGT) monolayer was systematically investigated by density functional theory. The structures, energy, charge transfer, work function, and electronic and magnetic properties of the gas molecule adsorbed Cr2Ge2Te6 monolayers were explored. It has been found that the adsorption of gas molecules significantly influences the electronic and magnetic properties of a CGT sheet. It was observed that the adsorption of molecules could effectively enhance the ferromagnetism and Curie temperature (T-C) of the CGT sheet. Notably, a remarkable enhancement of ferromagnetism and T-C by 38% and 32% was achieved by the adsorption of NO and NO2, respectively. Moreover, NO2 adsorbed CGT exhibits a semiconductor-to-metal transition. The enhanced ferromagnetism and tunable electronic structure could be ascribed to the considerable charge transfer as well as to the alignment of the frontier molecular orbital. The outcome of this study reveals not only exciting insights into the environmental effect on 2D magnets but also provides a new candidate as a NO2 gas sensor.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Materials Chemistry C
ISSN
2050-7526
e-ISSN
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Volume of the periodical
7
Issue of the periodical within the volume
17
Country of publishing house
GB - UNITED KINGDOM
Number of pages
10
Pages from-to
5084-5093
UT code for WoS article
000466777900013
EID of the result in the Scopus database
2-s2.0-85065232756