Synthesis and Structural Characterisation of an N-Phosphanyl Ferrocene Carboxamide and its Ruthenium, Rhodium and Palladium Complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F20%3A10413840" target="_blank" >RIV/00216208:11310/20:10413840 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=CP6mSOffnp" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=CP6mSOffnp</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/cplu.202000303" target="_blank" >10.1002/cplu.202000303</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis and Structural Characterisation of an N-Phosphanyl Ferrocene Carboxamide and its Ruthenium, Rhodium and Palladium Complexes
Original language description
[((Diphenylphosphanyl)amino)carbonyl]ferrocene (1) has been synthesized and coordinated to light platinum metals, ruthenium, rhodium and palladium, in diverse coordination modes. Specifically, compound1was used to prepare the following phosphane complexes, [(η(6)-mes)RuCl2(1-κP)], [(η(5)-C5Me5)RhCl2(1-κP)],trans-[PdCl2(1-κP)(2)], and [(L-NC)PdCl(1-κP)] (mes=mesitylene, L-NC=[2-(dimethylamino-κ N)methyl]phenyl-κC-1). They were subsequently converted into cationic O,P-chelate complexes by halide abstraction with AgClO(4)and into neutral O,P-chelate complexes by deprotonation with potassiumtert-butoxide. All coordination compounds and phosphane chalcogenides1E(P-bound chalcogen atom E=O, S and Se), which were also synthesised, were structurally characterised using spectroscopic methods (IR, multinuclear NMR and ESI MS) and single-crystal X-ray diffraction analysis. The electrochemical behaviour of the prepared compounds was studied by cyclic voltammetry, and the (L-NC)Pd-1complexes were further studied by Mossbauer spectroscopy.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
<a href="/en/project/GA19-09334S" target="_blank" >GA19-09334S: Uncoventional ferrocene phosphines</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemPlusChem
ISSN
2192-6506
e-ISSN
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Volume of the periodical
85
Issue of the periodical within the volume
6
Country of publishing house
DE - GERMANY
Number of pages
14
Pages from-to
1325-1338
UT code for WoS article
000544057700027
EID of the result in the Scopus database
2-s2.0-85086852568