Novel ferrocenyl functionalised phosphinecarboxamides: synthesis, characterisation and coordination

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F20%3A10413844" target="_blank" >RIV/00216208:11310/20:10413844 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=YSJI_PstXh" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=YSJI_PstXh</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d0dt01908a" target="_blank" >10.1039/d0dt01908a</a>

Result language
angličtina
Original language name
Novel ferrocenyl functionalised phosphinecarboxamides: synthesis, characterisation and coordination
Original language description
The synthesis of two novel ferrocenyl-substituted phosphinecarboxamides, FcNHC(O)PH2(1; Fc = ferrocenyl) and FcCH(2)NHC(O)PH2(2), is reported. These two primary phosphines were obtained by the reaction of aminoferrocene with sodium 2-phosphaethynolate in the presence of a proton source or, directly, from aminomethylferrocene hydrochloride and sodium 2-phosphaethynolate. Their ability to act as ligands was probedviareactions of1with rhodium(iii) and ruthenium(ii) precursors. The isoelectronic metal complexes [(η(5)-C5Me5)RhCl2(1-κP)] and [(η(6)-mes)RuCl2(1-κP)] were obtained. Treatment of these compounds with a base resulted in HCl elimination to afford phosphide-bridged dirhodium and diruthenium complexes highlighting that on coordination to a metal, the P-H bonds of these phosphinecarboxamides become increasingly protic.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
<a href="/en/project/GA19-09334S" target="_blank" >GA19-09334S: Uncoventional ferrocene phosphines</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)