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From pipemidic acid molecular salts to metal complexes and BioMOFs using mechanochemistry

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F21%3A10427960" target="_blank" >RIV/00216208:11310/21:10427960 - isvavai.cz</a>

  • Result on the web

    <a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=.8n0j9Z2us" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=.8n0j9Z2us</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/d0ce01533d" target="_blank" >10.1039/d0ce01533d</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    From pipemidic acid molecular salts to metal complexes and BioMOFs using mechanochemistry

  • Original language description

    Mechanochemistry has been assuming a major role in chemistry over the last years. Its potential in a wide variety of reactions is undeniable nowadays, contributing to sustainable chemistry and, at the same time, leading to lower reaction time, higher selectivity and novel reactivity. Herein we disclose new solid forms of pipemidic acid, an antibiotic against which bacteria have been developing resistance mechanisms, obtained by mechanochemistry. These forms are molecular salts with glycolic, oxalic and (R)- and (S)-camphorsulfonic acids, as well as a Cu(II) complex exhibiting a 1D hydrogen bonded network. To prove the importance of the technique, we present here also the rapid and high yielding mechanochemical synthesis of a previously reported Ag metal-organic framework with pipemidic acid.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    CrystEngComm

  • ISSN

    1466-8033

  • e-ISSN

  • Volume of the periodical

    23

  • Issue of the periodical within the volume

    5

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    11

  • Pages from-to

    1099-1109

  • UT code for WoS article

    000616376500004

  • EID of the result in the Scopus database

    2-s2.0-85100753319