Exploring Supramolecular Gels in Flow-Type Chemistry-Design and Preparation of Stationary Phases
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216208%3A11310%2F21%3A10430799" target="_blank" >RIV/00216208:11310/21:10430799 - isvavai.cz</a>
Result on the web
<a href="https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=X6Qq6ueeHs" target="_blank" >https://verso.is.cuni.cz/pub/verso.fpl?fname=obd_publikace_handle&handle=X6Qq6ueeHs</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.iecr.1c01914" target="_blank" >10.1021/acs.iecr.1c01914</a>
Alternative languages
Result language
angličtina
Original language name
Exploring Supramolecular Gels in Flow-Type Chemistry-Design and Preparation of Stationary Phases
Original language description
Two major challenges facing chemical synthesis are product isolation and catalyst recovery. One method to overcome these challenges is to perform the synthesis in a flow system with a catalytic stationary phase. However, the polymeric catalytic materials used in flow systems are often laborious to produce. In this study, we investigate a novel supramolecular gel as a catalytic stationary phase material. The gel is based on a modular, easy to synthesize, oxotriphenylhexanoate (OTHO) gelator comprised of a catalytic unit designed to catalyze the Knoevenagel reaction. The catalytic organogel enhances the rate of product formation and can be reused five times. Use of the OTHO to construct catalytic gels is a flexible technique that can be utilized to improve product isolation and reduce wastage of the catalyst.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/EF17_050%2F0008466" target="_blank" >EF17_050/0008466: Improvement of internationalization in the field of research and development at Charles University, through the support of quality projects MSCA-IF</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Industrial and Engineering Chemistry Research
ISSN
0888-5885
e-ISSN
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Volume of the periodical
60
Issue of the periodical within the volume
28
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
10056-10063
UT code for WoS article
000677542700004
EID of the result in the Scopus database
2-s2.0-85111255962