Silica gel-immobilized multidisciplinary materials applicable in stereoselective organocatalysis and HPLC separation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22310%2F18%3A43916382" target="_blank" >RIV/60461373:22310/18:43916382 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c7ra12658a" target="_blank" >http://dx.doi.org/10.1039/c7ra12658a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c7ra12658a" target="_blank" >10.1039/c7ra12658a</a>
Alternative languages
Result language
angličtina
Original language name
Silica gel-immobilized multidisciplinary materials applicable in stereoselective organocatalysis and HPLC separation
Original language description
In this pilot study, we present novel bifunctional silica gel-immobilized materials applicable as heterogeneous organocatalysts and stationary phases in HPLC. The materials provided high stereoselectivity in both batch and continuous flow catalysis of a model Michael addition (cyclohexanone to (E)-beta-nitrostyrene). In the batch reaction, the catalysts proved their sustainable catalytic activity over five consecutive recycling experiments. Under continuous flow reaction conditions, the catalytic activity was found to be superior to the batch reaction, and moreover, the same immobilized materials were utilized as stationary phases in HPLC showing very good chemoselective separation of model acidic analytes.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/GJ16-17689Y" target="_blank" >GJ16-17689Y: Novel chiral ion exchange-type stationary phases for enantiomer separation</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
RSC Advances
ISSN
2046-2069
e-ISSN
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Volume of the periodical
8
Issue of the periodical within the volume
3
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
1174-1181
UT code for WoS article
000419371200003
EID of the result in the Scopus database
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